The Bimolecular Decay of the a - Hydroxymethylperoxyl Radicals in Aqueous Solution
نویسنده
چکیده
a-Hydroxymethylperoxyl Radical, Pulse Radiolysis, Conductivity, Oxydation of Methanol The bimolecular decay of the hydroxymethylperoxyl radical in aqueous solution (k = 2.1 x 109 M_1s_1) leads mainly (80%) to one molecule of hydrogen peroxid and to two molecules of formic acid. 2 HOCHsOO-> H202 + 2 HCOOH Deuterium kinetic isotope effects show that the decay occurs at room temperature via a short lived (t < 10-4 s) tetroxid.
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